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Purely Organic Mixed-Valence Molecules with Nanometric Dimensions Showing Long-Range Electron Transfer. Synthesis, and Optical and EPR Studies of a Radical Anion Derived from a Bis(triarylmethyl)Diradical

Bonvoisin, Jacques; Launay, Jean-Pierre; Rovira, Concepció and Veciana, Jaume (1994) Purely Organic Mixed-Valence Molecules with Nanometric Dimensions Showing Long-Range Electron Transfer. Synthesis, and Optical and EPR Studies of a Radical Anion Derived from a Bis(triarylmethyl)Diradical. Angewandte Chemie International Edition, pp. 2106-2109.

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Document available online at: https://hal.archives-ouvertes.fr/hal-01741127


Summary

Both optical and thermal electron transfer were examined in detail in radical anion 1, which was generated electrochemically from the analogous stable diradical. Optical electron transfer is induced at λ = 1400 nm. The results are discussed in the context of the Hush‐Marcus theory.


EPrint Type:Journal paper
Keywords:Mixed-valence organic compounds (en), Long-range electron transfer (en), Spectroelectrochemistry (en), Diradical (en)
Subjects:"Organics" in general
Research affiliation: France > INRAe - Institut national de recherche pour l’agriculture, l’alimentation et l’environnement
ISSN:ISSN: 1433-7851
DOI:10.1002/anie.199421061
Project ID:HAL-INRAe
Deposited By: PENVERN, Servane
ID Code:41402
Deposited On:12 Aug 2021 10:38
Last Modified:12 Aug 2021 10:38
Document Language:English

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